Guy on baking

 

Air fryers versus ovens

Despite their name, air fryers bake their food rather than frying it. In effect, they are simply small fan-forced ovens. The key difference between air fryers and ovens is simply size.

Because of their smaller size, air fryers typically take less time to heat the air and also have more rapid air flow. This, in turn, means that they typically cook faster than fan-forced ovens, say 25-50% faster. Furthermore, the use of a basket in which the food is placed, helps air flow and thus evenness of the cooking. They also use less energy, occupy less space and heat up the kitchen less.

Because of their larger size, ovens can cook multiple dishes at the same time. They can also cook in ways other than fan-forced and are therefore more flexible.

Finally, you will almost definitely already have an oven but may well not (yet) have an air fryer.

Baker’s yeast versus sourdough starter

Baker’s yeast is a particular species of yeast, Saccharomyces cerevisiae, which converts sugar into carbon dioxide and ethanol. The carbon dioxide gas causes the dough to rise, whilst the ethanol either evaporates or is left in the bread. The heat used whilst baking then kills off the yeast. It is the same species, but a different strain, as that used in alcoholic fermentation. It is a manufactured product, grown in vats. It has only been around for the last 150-250 years.

Baker’s yeast is available in a number of different forms, the main differences being the moisture content. The most common form for non-commercial bakers in Australia is ‘dry yeast’, where live yeast cells are encapsulated in a thick jacket of dry, dead cells with some growth medium. Before use, dry yeast is re-hydrated, such that the live yeast can escape its jacket. Note that nutritional yeast is ‘deactivated’ (i.e. dead) Saccharomyces cerevisiae, which is eaten for its taste or nutritional value.

A sourdough starter is a much more complicated substance than baker’s yeast. Whilst it will usually contain Saccharomyces cerevisiae, it will also contain a variety of other yeasts. It will also contain lactic acid bacteria, which convert carbohydrates into lactic and other acids plus other substances (it is these acids that give sourdough its sour/tangy taste). And the yeast and bacteria will be in a mixture of flour and water, on which they have been feeding.

A sourdough starter is created by simply mixing flour and water together and leaving it loosely covered but out in the open, after which various yeasts and lactic acid bacteria will, over time, enter from the air and start to feed and breed. Then, regularly remove around half of the starter and add new flour and water, so that the yeasts and bacteria have something new to eat.

Because baker’s yeast is a single substance, the results from using it are very predictable. It will rise bread faster than a sourdough starter. It is also easily available, easy to use and has a long shelf life.

Because a sourdough starter is a mix of substances which will differ somewhat from starter to starter, its results are less predictable. It also imparts a taste to the bread, which some/many people prefer, and results in a chewier texture. There is general agreement that sourdough starters, and more generally long-time fermentation processes, improve bread digestibility. They may also break down some of the gluten. However, a sourdough starter will rise the bread less quickly (and sometimes much less quickly) and requires time and effort to create and maintain.

Baker’s yeast and sourdough starter are interchangeable in most recipes, but non-trivially so. One rule of thumb is that 100g sourdough starter equates to around 3½g (1+ teaspoons) baker’s yeast plus 50g wet ingredients plus 50g dry ingredients.

Baking soda versus baking powder

Baking soda is sodium bicarbonate (aka bicarbonate of soda). When it is brought into contact with an acid, a chemical reaction occurs that produces bubbles of carbon dioxide which, in turn, have a leavening effect.

Baking powder comprises a base (most commonly baking soda) plus a dry acid (most commonly cream of tartar) plus a buffer (most commonly corn starch) to stop the base and the acid interacting. When it is brought into contact with a liquid, the same chemical reaction occurs as for baking soda.

Most current baking powders produce further carbon dioxide when heated and are thus known as double-acting baking powders.

Wikipedia lists 3 common bases for baking powder and 9 common acids.

Baking soda and baking powder can potentially be substituted for each other but only if you know what you are doing.

Baking soda and baking powder work much more quickly than yeast and don’t produce any flavours. Although yeast also leavens through the production of carbon dioxide, the underlying chemistry is completely different.

Baking powder was invented in 1843 by someone called Alfred Bird, who was motivated to develop a yeast-free leavener because his wife was allergic to yeast. He also invented egg-free custard as his wife was also allergic to eggs. What a husband!

Butter: standard vs cultured vs clarified

Butter is the result of agitating/churning cream up to the point where the solids (butter) separate from the liquid (buttermilk). This separation happens because the churning process causes the fat in the cream to pool together. Butter is thus mostly fat (80%) and water.

Cultured butter is the result of the same process except that the cream is somewhat fermented before the churning. Historically (i.e. before refrigeration), most butter was effectively cultured because the cream was usually collected from several milkings and was therefore several days old and somewhat fermented by the time it was made into butter. Also, European butter is often cultured. The fermentation process in cultured butter produces additional aromatic compounds which apparently makes the butter more ‘buttery’ tasting.

Clarified butter (aka ghee) is where almost all of butter’s water and milk solids are removed, leaving almost pure butterfat. It is made by simmering butter, resulting in the water evaporating and the milk solids separating out. This heating process apparently also produces antioxidants that help protect the clarified butter from rancidity, meaning it has a much longer shelf life than standard butter. Ghee is more ‘nutty tasting’ and aromatic than standard butter.

In terms of baking, cultured butter can always be used instead of standard butter and will make the end product taste a bit more ‘buttery’. It also tends to create a finer crumb texture. But, because it is typically more expensive than standard butter, its use is often restricted to recipes where the butter is an important ingredient from a taste perspective, such as in croissants, brioche and shortbreads or spread on toast or bread.

Ghee should not be used as a substitute in baking where the recipe calls for cold butter cut in pieces (e.g. pie crusts and bread) or for icings/frostings. It can be used in other baking recipes, for example where the butter is either melted or creamed, but the substitution is non-trivial because it can affect both the taste and the texture of the end result.

Ghee is commonly used in Indian cuisine.

Finally, note that ghee and cultured butter both have a higher smoke point than standard butter. This means that they are better suited than standard butter for sauteing, frying and searing meat or vegetables without worrying about smoking up your kitchen.

Butter vs margarine vs shortening vs lard & tallow

Butter is made from the fat and protein components of churned cream which is, in turn, the higher-fat layer skimmed from the top of un-homogenised milk. As such, butter is mostly (at least 80%) fat, and most of this is saturated fats.

Margarine is an emulsion of fat and water, with most of the fat usually being unsaturated. Most margarine nowadays is made from vegetable oil (although it was originally made from animal fats) and is vegan. Some margarines, however, contains some dairy and others contain other animal products. For this reason, some vegan margarines are called something else, such as ‘vegan spreadable’ or ‘dairy free buttery spread’.

Shortening is technically any fat that is a solid at room temperature. Nowadays, it is usually made from hydrogenated vegetable oils. It is 100% fat and has no water content. The most popular shortening in Australia is Copha, which is 99% coconut oil.

Lard and tallow are effectively animal versions of shortening, made from pig and cattle/sheep respectively. They used to be popular but have now been largely replaced by vegetable shortening.

The main reason for using butter, margarine or shortening in baking is to make the baked goods more tender (think brioche versus baguette). This is due to the fats, which prevent the gluten forming long strands (which is why ‘shortening’ is so called).

Butter has a distinct taste, whereas margarine may or may not have a taste depending on its composition, and shortening is virtually flavourless.

Butter has a lower melting point than shortening and it therefore causes baked goods to spread more and have less height. More generally, the use of butter, margarine or shortening can result in somewhat different textures and mouth feels.

These varying characteristics mean that the end product can be a bit different depending on whether butter, margarine or shortening is used. For example, if you want your biscuits to be thin and chewy, you might use butter whereas if you want them thick and soft, you might use shortening.

Butter is typically more expensive than margarine which, in turn, is typically more expensive than shortening.

Butter is mostly saturated fats, which can be a health concern. Some margarines contain artificial ingredients, which can be a concern for those who prefer to use natural ingredients.

Substitution should be done on the basis of equal amounts of fat. So, for example use 80g of shortening (which is 100% fat) instead of 100g of butter (which is usually around 80% fat) or vice versa. With shortening, potentially add a bit of water to make up for its lack of water. With margarine, read the label to find out the fat percentage.

Finally, margarine and shortening are usually vegan whilst butter obviously never is.

Cornstarch versus cornflour

In Australia and the UK, the words cornstarch and cornflour are used interchangeably to refer to the starch derived from corn grain.

In the USA, however, the word cornflour is used to refer to a flour made from corn kernels.

Flours: whole grain vs wholemeal vs white

Let’s start with some definitions.

Flour is technically any powder made by grinding raw grains, roots, beans, nuts or seeds. The word ‘meal’ can be used as either a synonym for ‘flour’ or as having a slightly coarser particle size than flour.

Flours are used to make many different foods. Cereal flour, particularly wheat flour, is the main ingredient of bread.

Historically, cereal flour comprised all parts of the grain, namely the germ (the seed embryo), the endosperm (the nutrition for the embryo) and the bran (the hard layers that hold the grain together). Nowadays, the germ is usually removed as that substantially increases shelf life. ‘Whole grain’ is where the germ has not been removed. ‘White’ or unspecified flour is essentially where the bran is also removed, whilst ‘whole meal’ flour is where the bran has not been removed. Note that bleaching of flour is not legal in Australia (unlike in the USA).

 
Whole grain flour
Wholemeal flour
White or unspecified flour
Endosperm
X X X
Bran
X X  
Germ
X    

 

‘Self-raising’ flour (as opposed to plain flour) is where a leavening agent, usually baking powder, has been added. What the Americans call ‘all-purpose flour’ is the same as what we call plain flour.

Wheat flour is usually made from common wheat (Triticum aestivum). Semolina is made from durum/pasta wheat (Triticum durum). Spelt flour is made from hulled wheat (Triticum spelta).

Flours labelled as ‘baker’s’, ‘bread’, ‘pizza’ or ‘strong’ are typically made from varieties of wheat (sometimes termed ‘hard’ varieties) which contain comparatively high levels of protein.

Except for corn/maize, wheat and other cereal flours contain gluten. It is the gluten which gives dough its elasticity, helping it to rise and keep its shape. Essentially, it traps the carbon dioxide bubbles created by the leavening agent during cooking, causing the dough to rise. And it coagulates when heated, giving the dough shape.

Up to 15% of the population have some level of gluten intolerance and this has created a demand for gluten-free flours. Here are some of the gluten-free flours that my local shops sell: almond, banana, buckwheat, cassava, chick pea, coconut, flax seed, hazelnut, oat, potato, rice and sweet potato. Because these flours lack the very product (gluten) that gives dough its elasticity, both their suitability for various types of baking and their ingredients will differ from flour to flour. Most flour labelled as simply gluten-free is made from rice together with various starches and other ingredients.

Finally, at least in Australia, corn flour is rather different than the other flours and is usually used for thickening.

So, what flour to use when baking?

Most recipes will specify which of plain or self-raising flour to use. If not specified, plain flour can be assumed. If self-raising flour is specified but, for one reason or another you don’t want to use it, you can in principle create your own by adding baking powder to plain flour, but this is non-trivial.

Wholemeal flour can be used whenever plain flour is specified. Because it contains more fibre, the end result is a bit closely textured and a bit darker in colour, plus it has a few more nutritional elements.

For those with some gluten intolerance, gluten-free flour can be used as a substitute for standard flour but the end result may well be a bit different in terms of both rise/shape and taste/texture. Also, gluten-free flours often contain starches (which absorb liquid) so a gluten-free recipe may well call for more liquid and produce looser batters. Finally, different gluten-free flours can be very different than others and thus personal experimentation may well be required to find one that suits you.

Honey versus sugar

Sugar is 50% fructose and 50% glucose. Honey is around 40% fructose, 30% glucose, 20% water and 10% other substances (including pollen and minerals). So, whereas sugar is a simple substance, honey is much more complex.

Because of the 10% of other substances, honey has a taste that goes beyond sweetness and this means, for example, that baked goods taste somewhat different if made using honey rather than sugar. Some of these other substances in honey may also have some health benefits.

In sugar, the fructose and glucose are bound together to form sucrose. In honey, however, the fructose and glucose are mostly unbound. One byproduct of this is that honey actually tastes sweeter than sugar.

Honey has an ability to retain moisture and baked goods made using honey may stay therefore moist and tender for longer periods of time than those made using sugar. This can be important for recipes where dryness is a concern, such as whole-grain bread or muffins.

Honey is about 50% heavier than sugar.

When substituting honey for sugar in a recipe, the formulae to use are not obvious because, as discussed above, honey has less sugars but tastes sweeter and is much heavier. A brief survey of the Internet suggests that substituting equal weights (not volumes) is reasonable. Because of the 20% water in honey, reduce the liquid in your recipe by a fifth of a cup for every cup of honey used. And potentially add a bit of baking soda to counteract the acidity of the honey.

Muffins versus cupcakes

Different people can assume slightly different meanings for the same word, so what I think of as a muffin might be slightly different than what you think of as a muffin. And the similarities of muffins and cupcakes are such that there might be things that I would call muffins that you would call cupcakes, and vice versa.

Muffins and cupcakes are both made with flour, eggs, milk and sugar. Within this, some of the common recipe differences are set out in the table below.

 
Cupcakes
Muffins
Savoury or sweet? always sweet sweet or savoury
Ingredients always plain or self-raising flour sometimes wholewheat flour
butter either butter or vegetable oil
tend to have less milk and more eggs tend to have more milk and less eggs
tend to have more sugar and more fat tend to have less sugar and less fat
never have bits in often have bits in (dried fruits, nuts, etc)
Method The creaming method: add the ingredients one by one and whisk them thoroughly, resulting in a smooth, fluffy batter.
 
(Cupcakes are miniature cakes.)
Mix the dry ingredients together. Mix the wet ingredients together (butter is treated as a wet ingredient and therefore melted). Gently combine and, after a couple of quick stirs, you’ll get a thick, lumpy batter.
 
(Muffins are a type of quick bread.)
Result soft and spongy moist and dense
Frosting, etc? often never
Serving style? always cold can be served warm

 

Sour cream versus yoghurt

Sour cream and yoghurt are both fermented dairy products, with sour cream being fermented cream and yoghurt being fermented milk. They typically use different bacteria for the fermentation, which gives them somewhat different tastes. Creme fraiche is effectively a type of sour cream. Greek yoghurt is yoghurt that has been strained to remove some of its whey, thus making it thicker (and more similar in consistency to sour cream).

In both cases, the bacterial fermentation turns the sugars into lactic acid.

The differences between sour cream and yoghurt are less than the differences between some cheeses – it is effectively a historical accident that, unlike cheese, they have completely different names.

Because of their different source substance (cream versus milk), sour cream has much more fat (and therefore calories) than yoghurt. By contrast, it typically has less protein.

It is widely agreed that sour cream and yoghurt can be substituted for each other in recipes using a 1:1 substitution. However, note that:

  • The flavour might be slightly different.
  • Greek yoghurt is the closest in texture to sour cream.
  • You can effectively turn plain yoghurt into Greek yoghurt by straining out some of the whey using a piece of cheesecloth.
  • Having less fat, yoghurt is more likely to curdle when heated.
  • When substituting yoghurt for sour cream, you can also add some butter to raise the fat content.

Possible vegan substitutes for sour cream include:

  • Coconut cream, created by skimming off the top of coconut milk and adding some acid (e.g. vinegar or lemon juice) and salt.
  • Silken tofu, where you blend firm silken tofu with some acid (e.g. vinegar or lemon juice).

Sugar: brown vs white vs caster vs icing vs raw

White sugar is basically 100% sucrose (C12H22O11), where it has been produced by ‘refining’ either beet sugar or cane sugar to remove the molasses and other substances. It is a crystalline substance, which comes in various crystal sizes. The largest crystal size is usually called granulated or table sugar, the next size down is usually called caster or superfine sugar, and the smallest crystal size is usually called icing or powdered sugar. Icing sugar often also has a small amount (2-5%) of anti-caking agent, such as corn starch, added to prevent clumping.

Brown sugar basically comprises sucrose (at least 90%) plus molasses (3-10% by weight). Traditionally, it was produced by only partially refining either beet sugar or cane sugar, with a number of named varieties depending on the precise process used (e.g. demerara, muscovado, rapadura and turbinado). Nowadays, however, brown sugar is often produced by adding back in sugarcane molasses to completely refined white sugar, with two main varieties (light brown and dark brown) depending on the amount of molasses.

Molasses (which is a singular noun, not plural) is a complex substance comprising around 75% carbohydrates, 22% water and 3% other things. As well turning the sugar brown, the molasses make it moister and softer.

Finally, there is ‘raw sugar’. Different people seem to use the term ‘raw sugar’ to describe slightly different things but the most common usage is that it is ‘partially refined’ sugar, where most of the molasses has been removed but the sugar has not been bleached.

In baking, let’s assume that the default is to use white granulated/table sugar, if only because of the cost. The question then becomes when should you potentially use the other sugars.

Caster sugar tastes the same as table sugar but, because of its smaller crystals, it dissolves more easily. This usually doesn’t make much difference but it does make caster sugar arguably more suitable in cases such as syrups, glazes, frostings, fillings and delicate pastries (such as sponge cakes). Caster sugar is a bit denser than table sugar so, if you are being accurate, recipe substitution should be by weight rather than by volume.

As the name suggests, icing sugar is usually used for icings, frostings or dustings. Also, because it dissolves the most easily of the white sugars, some people keep it on hand to add to drinks. Again, any recipe substitution should be by weight. Icing sugar may contain some corn starch or similar as an anti-caking agent, in which case it is sometimes called that ‘icing mixture’ or similar; this can lead to somewhat unexpected results when baking.

In comparison with white sugar, the molasses in brown sugar give it both a somewhat different flavour and a somewhat different texture. It also caramelises more readily. The American Sugar Association recommends using dark brown sugar in recipes that have a “richer flavour profile such as spice cakes, gingerbreads and barbecue sauces. On the other hand, recipes calling for light brown sugar include sweet sauces, marinades and rubs.” For texture reasons, brown sugar is also sometimes used as a topping over puddings. Because brown sugar is nearly all sucrose, recipe substitution with white sugar can be 1:1 by weight.

Alternatives to sugar divide into two main groups: 1) substances which contain a lot of sucrose/glucose/fructose but which have been made from plants other than sugarbeet or sugarcane; and 2) non-sugar sweeteners. The obvious substance in the first group is honey (as discussed in an earlier section of this page), with other possibilities including coconut sugar, dates, fruit purees, maple syrup, maple sugar and palm sugar. Non-sugar sweeteners are substances which taste sweet to humans but do not contain any sucrose/glucose/fructose. Examples include the synthetic saccharin and the natural stevia. Substituting any of these for table sugar in a recipe is non-trivial.

The roles of acids in baking

Acids are compounds which give off hydrogen ions (H+) when they are dissolved in water. These hydrogen ions are then free to interact with other molecules in solution. In baking, these chemical reactions can take a number of forms:

  1. Activation of alkaline ingredients: for example, baking soda is an alkaline substance which reacts with the acid, releasing carbon dioxide as a byproduct and thus causing a cake to rise. (Read about baking soda versus baking powder).
  2. Protein alteration: hydrogen ions disrupt the bonds that keep gluten and other proteins folded into specific shapes and cause them to unravel. This undoing usually beneficially tenderises a cake but, in excess, it can also cause problems to its structure.
  3. Starch modification: acids cause starches to break down and gel at a lower temperature. This can cause a cake to set more quickly but with less structural support.
  4. Browning troubles: acidic ingredients interfere with the reactions that cause browning in baked foods and can result in pale cakes.

To help reduce unwanted side effects, it is generally recommended that you usually delay the addition of any acid until late in the preparation of a cake.

Acids can also affect the taste and flavour of the final product, adding sour or tangy notes and/or balancing sweetness. The effects will depend on which acid is used, with the most common being:

  • Acetic (vinegar).
  • Ascorbic (vitamin C).
  • Citric (lemon juice and other citrus).
  • Lactic (fermented milk products).
  • Malic (from various fruits but usually bought as a powder).
  • Tartaric (from grapes but usually bought as a powder).

Outside of baking, acids can also act as a preservative, for example in pickling.

  5 Responses to “Guy on baking”

  1. Great post, Guy – thanks!
    Would love to hear more about molasses and other sweeteners.
    Also the nutritional differences between honey and sugar (and molasses etc).
    I would use honey for all of my baking if budget wasn’t an issue. Maybe the price of sugar should be put up.

    • Hello Guy. According to my mum, it’s ‘icing mixture’ that contains cornflour, to keep it from forming lumps … pure icing sugar is just sugar and goes lumpy after a while (lumps dissolve when water added). She always told me for a certain biscuit we made at Christmas to make sure I was getting pure icing sugar.

      • Thanks, Lucinda.

        I have slightly re-worded the relevant paragraph.

        I sometimes find the nuances of precise terminology in cooking rather difficult to fully understand. For example, I have just gone onto the Coles website and searched for ‘icing sugar’. There were 4 results, each with slightly different terminology, namely Pure Icing Sugar, Icing Sugar Mixture, Sugar Icing Mixture and Soft Icing Mixture. Of these 4, only 1 has a list of ingredients (Soft Icing Mixture, with ingredients sugar and starch).

        The Wikipedia page on icing sugar includes the following sentence “Icing sugar … usually contains between 2% and 5% of an anti-caking agent.”

  2. This was a really interesting article Guy. Many thanks. Now my question … where does raw sugar come in this discussion?

    • Hi Kerry,

      Just when I thought that I didn’t need to do any more research!

      In response to your question, I’ve added the following para to the article: “Finally, there is ‘raw sugar’. Different people seem to use the term ‘raw sugar’ to describe slightly different things but the most common usage is that it is ‘partially refined’ sugar, where most of the molasses has been removed but the sugar has not been bleached.”

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